Cookies

We use cookies to ensure that we give you the best experience on our website. By continuing to browse this repository, you give consent for essential cookies to be used. You can read more about our Privacy and Cookie Policy.


Durham e-Theses
You are in:

Novel fluorocarbon iodides

Copin, Elodie (2002) Novel fluorocarbon iodides. Doctoral thesis, Durham University.

[img]
Preview
PDF
3696Kb

Abstract

This work describes the three-step synthesis of some new fluorocarbon iodides. First, functionalisations of carbon-hydrogen bonds, using fluorinated alkenes via a free radical chain mechanism, were carried out. The HFP-adducts were then further functionalised by elimination of hydrogen fluoride to yield a series of fluoroalkenes, which were then converted to fluorocarbon iodides by means of a mixture of IF(_5)/I(_2) (corresponding to iodine monofluoride formed in situ). Chemistry of the new fluorocarbon iodides was investigated, especially in reactions with thiols.

Item Type:Thesis (Doctoral)
Award:Doctor of Philosophy
Thesis Date:2002
Copyright:Copyright of this thesis is held by the author
Deposited On:01 Aug 2012 11:40

Social bookmarking: del.icio.usConnoteaBibSonomyCiteULikeFacebookTwitter