Copin, Elodie (2002) Novel fluorocarbon iodides. Doctoral thesis, Durham University.
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Abstract
This work describes the three-step synthesis of some new fluorocarbon iodides. First, functionalisations of carbon-hydrogen bonds, using fluorinated alkenes via a free radical chain mechanism, were carried out. The HFP-adducts were then further functionalised by elimination of hydrogen fluoride to yield a series of fluoroalkenes, which were then converted to fluorocarbon iodides by means of a mixture of IF(_5)/I(_2) (corresponding to iodine monofluoride formed in situ). Chemistry of the new fluorocarbon iodides was investigated, especially in reactions with thiols.
| Item Type: | Thesis (Doctoral) |
|---|---|
| Award: | Doctor of Philosophy |
| Thesis Date: | 2002 |
| Copyright: | Copyright of this thesis is held by the author |
| Deposited On: | 01 Aug 2012 11:40 |
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